Replacement metal gate structure for CMOS device

ABSTRACT

A CMOS device that includes an nFET portion, a pFET portion and an interlayer dielectric between the nFET portion and pFET portion. The nFET portion has a gate structure having a recess filled with a conformal high-k dielectric, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer in direct physical contact with the barrier layer and a gate metal filling the remainder of the recess. The pFET portion has a gate structure having a recess filled with a conformal high-k dielectric, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer on the barrier layer, a third titanium nitride layer in direct physical contact with the second titanium nitride layer and a gate metal filling the remainder of the recess.

RELATED APPLICATION

This application is a divisional of U.S. patent application Ser. No. 13/676,575, filed Nov. 14, 2012, entitled “REPLACEMENT METAL GATE STRUCTURE FOR CMOS DEVICE” and is related to U.S. patent application Ser. No. 13/676,483, filed Nov. 14, 2012, entitled “REPLACEMENT METAL GATE STRUCTURE FOR CMOS DEVICE”.

BACKGROUND

The exemplary embodiments relate to a manufacturing process for replacement metal gate CMOS devices and, more particularly, relate to a simpler manufacturing process to obtain quarter-gap pFET.

Today's integrated circuits include a vast number of devices. Smaller devices and shrinking ground rules are the key to enhance performance and to reduce cost. As FET (Field Effect Transistor) devices are being scaled down, the technology becomes more complex, and changes in device structures and new fabrication methods are needed to maintain the expected performance enhancement from one generation of devices to the next.

Device performance may be enhanced by the use of metal gates and high-k dielectric materials.

BRIEF SUMMARY

The various advantages and purposes of the exemplary embodiments as described above and hereafter are achieved by providing, according to a first aspect of the exemplary embodiments, a semiconductor substrate having an nFET portion, a pFET portion and an interlayer dielectric between the nFET portion and pFET portion. The nFET portion has a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer in direct physical contact with the barrier layer and a gate metal filling the remainder of the recess. The pFET portion has a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer on the barrier layer, a third titanium nitride layer in direct physical contact with the second titanium nitride layer and a gate metal filling the remainder of the recess.

According to a second aspect of the exemplary embodiments, there is provided a CMOS device having a semiconductor substrate having an nFET portion, a pFET portion and an interlayer dielectric between the nFET portion and pFET portion. The nFET portion has a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer in direct physical contact with the barrier layer and a gate metal filling the remainder of the recess, wherein the second titanium nitride layer is titanium-rich wherein titanium-rich is greater than 50 atomic percent titanium. The pFET portion has a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer on the barrier layer, a third titanium nitride layer in direct physical contact with the second titanium nitride layer and a gate metal filling the remainder of the recess, wherein the third titanium nitride layer is titanium-rich, wherein titanium-rich is greater than 50 atomic percent titanium. The gate metal that fills the remainder of each of the nFET recess and pFET recess comprises a first layer of titanium aluminum and a second layer of aluminum or tungsten.

BRIEF DESCRIPTION OF SEVERAL VIEWS OF THE DRAWINGS

The features of the exemplary embodiments believed to be novel and the elements characteristic of the exemplary embodiments are set forth with particularity in the appended claims. The Figures are for illustration purposes only and are not drawn to scale. The exemplary embodiments, both as to organization and method of operation, may best be understood by reference to the detailed description which follows taken in conjunction with the accompanying drawings in which:

FIGS. 1 to 11 illustrate a method of the exemplary embodiments of forming a CMOS structure wherein:

FIG. 1 illustrates dummy gate structures on nFET and pFET portions of a semiconductor substrate;

FIG. 2 illustrates forming spacers on the dummy gate structures;

FIG. 3 illustrates forming an interlayer dielectric layer;

FIG. 4 illustrates planarizing to remove the hard nitride mask of the dummy gate structures;

FIG. 5 illustrates removing the polysilicon (or amorphous silicon) of the dummy gate structures;

FIG. 6 illustrates removing the oxide of the dummy gate structures;

FIG. 7 illustrates sequentially depositing a gate dielectric, a first titanium nitride layer, a barrier layer and a second titanium nitride layer;

FIG. 8 illustrates defining a photoresist mask over the pFET portion;

FIG. 9 illustrates removing the second titanium nitride layer from the nFET portion only;

FIG. 10 illustrates depositing a third layer of titanium nitride on both the nFET and pFET portions; and

FIG. 11 illustrates depositing a titanium aluminum alloy and aluminum or tungsten on both the nFET and pFET portions.

FIG. 12 is a flow chart illustrating the process flow of the exemplary embodiments.

DETAILED DESCRIPTION

Typically, small FET devices with high-k dielectrics and metal gates require expensive complicated processing. It would be useful to find ways to simplify the fabrication process, while maintaining most of the performance benefits offered by such advanced structures. In addition, reduction of gate leakage current and improvement in thermal stability of nFET devices.

Referring to the Figures in more detail, and particularly referring to FIGS. 1 to 11, there is disclosed one or more methods for fabricating CMOS devices according to the exemplary embodiments.

In FIG. 1, gate stack structures are formed which become dummy gate structures in a replacement gate process of the exemplary embodiments. Blanket layers of an oxide, polysilicon (could also be amorphous silicon), and a nitride hard mask are deposited on a semiconductor substrate.

For purposes of illustration and not limitation, the oxide may be silicon oxynitride and conventionally deposited to a thickness of about 1 to 4 nanometers (nm). The polysilicon may be conventionally deposited to a thickness of about 100 nm. The nitride hard mask, such as silicon nitride, may be conventionally deposited to a thickness of about 50 nm.

The various layers of oxide, polysilicon and nitride hard mask may be conventionally patterned by a reactive ion etching (RIE) process resulting in a semiconductor structure 100 including a gate structure 102 on an nFET portion of the semiconductor structure 100 and a gate structure 104 on a pFET portion of the semiconductor structure 100. Each of the gate structures 102, 104 includes an oxide layer 106, a polysilicon layer 110 and a hard mask layer 112.

The semiconductor structure 100 further includes a semiconductor substrate 114 which may be a bulk semiconductor material or may be a semiconductor on insulator (SOI). The semiconductor material making up the semiconductor substrate may be a silicon material or any other semiconductor material.

Each of the gate structures 102, 104 may further include a source 116 and a drain 118 adjacent to the gate structures 102, 104 as is known in the art. Separating the nFET portion from the pFET portion may be an isolation region 120.

Referring now to FIG. 2, oxide or nitride spacers 122 have been conventionally formed on the nFET gate structure 102 and the pFET gate structure 104. Portions 126 of sources 116 not blocked by spacers 122 and portions 128 of drains 118 not blocked by spacers 122 may be ion implanted 124 followed by a dopant activation anneal.

An interlayer dielectric (ILD) 130 may be deposited and planarized, stopping on the nitride hard mask 112 of the gate structures 102, 104 as shown in FIG. 3. The ILD may be any conventional ILD such as an oxide.

The planarization process may continue to remove the nitride hard mask and expose the polysilicon 110 as shown in FIG. 4.

Referring now to FIG. 5, the polysilicon 110 may be removed from the gate structures 102, 104. The polysilicon 110 may be removed by a wet etching process such as tetramethylammonium hydroxide (TMAH), tetraethylammonium Hydroxide (TEAH) or ammonium hydroxide (NH₄OH). The polysilicon 110 may alternatively be removed by a combination of wet etching, using any of the foregoing etchants, and RIE.

Subsequently, as shown in FIG. 6, the oxide layer 106 may be removed from the gate structures 102, 104 by a wet etching process including a suitable etchant such as hydrofluoric acid (HF). The recesses 132, 134 resulting from the removal of the oxide layer 106, polysilicon layer 110 and hard nitride mask layer 112 may be filled with work function and metal gate materials to result in permanent gate structures 102, 104 in the nFET portion and pFET portion of the semiconductor structure 100. Recesses 132, 134 may also be called trenches.

Referring now to FIG. 7, a gate dielectric 136 may be conformally deposited by an atomic layer deposition (ALD) process or a chemical vapor deposition (CVD) process. The gate dielectric 136 preferably is a high dielectric constant (high-k) dielectric material and may be, for example, HfO₂. The thickness of the gate dielectric may be about 2 nanometers (nm). Thereafter, sequential layers of a first titanium nitride 138, a barrier layer 140 such as tantalum nitride and a second titanium nitride 142 may be conformally deposited by an ALD process so that the deposited layers 138, 140, 142 line the walls of the recesses 132, 134. The first titanium nitride layer 138 may have a thickness of about 2 nm, the barrier layer 140 may have a thickness of about 1 nm and the second titanium nitride layer 142 may have a thickness of about 5 nm.

The second titanium nitride layer 142 may serve as the work function metal for the pFET gate structure 104 so it may need to be removed from the nFET gate structure 102. Referring now to FIG. 8, the pFET gate structure 104 may be blocked off with a photoresist mask 144 that has been defined to cover the pFET portion and then the second titanium nitride layer 142 may be wet etched with, for example, a solution of hyrdrogen peroxide (H₂O₂), NH₄OH and water or a solution of H₂O₂ and water. The resulting gate structure 102 without the second titanium nitride layer 142 is shown in FIG. 9. The photoresist mask 144 may then be conventionally stripped.

Referring now to FIG. 10, a third titanium nitride layer 146 is deposited in both recesses 132, 134. The third titanium nitride layer 146 is in contact with the barrier layer 140 in the nFET gate structure 102 and in contact with the second titanium nitride layer 142 in the pFET gate structure 104. The third titanium nitride layer 146 may be conformally deposited by an ALD process. Thereafter, the third titanium nitride layer 146 may be subjected to a low temperature oxidation process, indicated by arrows 148, at 400° C. for 1 to 10 minutes in an oxidizing atmosphere. While not wishing to be held to any particular theory, it is believed that the low temperature oxidation renders the third titanium nitride layer 146 titanium-rich when combined with the oxygen gettering effect of titanium aluminum in the downstream process. Titanium-rich means that there is more than 50 atomic percent titanium.

Thereafter, now referring to FIG. 11, a titanium aluminum alloy 150 may be deposited in the recesses 132, 134 in direct contact with the titanium-rich titanium nitride 146 followed by a metal 152 such as aluminum or tungsten to fill the remainder of the recesses 132, 134. The semiconductor structure 100 may then be conventionally planarized to remove any overburden of the previously-deposited layers. The titanium aluminum alloy 150 may be deposited by physical vapor deposition (PVD) or atomic layer deposition (ALD) to a thickness of about 3 nm. The aluminum or tungsten 152 may be deposited by PVD (for aluminum) or CVD (for tungsten) to fill the remaining thickness of the recesses 132, 134.

The semiconductor structure 100 may undergo additional processing such as back end of the line processing to form finished semiconductor structures.

A summary of the exemplary embodiments is illustrated in FIG. 12. In a first processing step, box 202, dummy gate structures are formed on nFET and pFET portions of a semiconductor substrate.

Thereafter, spacers may be formed on the dummy gate structures, box 204.

An ILD may be deposited between the dummy gate structures and then planarized, stopping on the dummy gate structures, box 206.

The hard nitride mask, gate polysilicon (or amorphous silicon) and oxide of the dummy gate structures may be removed, boxes 208, 210, 212, respectively, leaving recesses in the nFET and pFET portions.

A gate dielectric, preferably a high-k gate dielectric, may be deposited in the recesses in the nFET and pFET portions, box 214.

A first layer of titanium nitride is deposited in the recesses, box 216, followed by a barrier layer such as tantalum nitride, box 218.

A second layer of titanium nitride is deposited in the recesses, box 220. This second layer of titanium nitride is the work function metal for the pFET portion.

The second layer of titanium nitride is subsequently removed from the nFET portion, box 222.

A third layer of titanium nitride may then be deposited in the recesses, box 224. This layer of titanium nitride may be titanium-rich due to a low temperature oxidation, box 226.

Then, additional metals are deposited to fill the recesses including titanium aluminum and then aluminum or tungsten, boxes 228 and 230 respectively.

Other modifications of the exemplary embodiments beyond those embodiments specifically described here may be made without departing from the spirit of the invention. Accordingly, such modifications are considered within the scope of the invention as limited solely by the appended claims. 

What is claimed is:
 1. A CMOS device comprising: a semiconductor substrate having an nFET portion, a pFET portion and an interlayer dielectric between the nFET portion and pFET portion; the nFET portion having a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer in direct physical contact with the barrier layer and a gate metal filling the remainder of the recess; and the pFET portion having a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer on the barrier layer, a third titanium nitride layer in direct physical contact with the second titanium nitride layer and a gate metal filling the remainder of the recess.
 2. The CMOS device of claim 1 wherein the first titanium nitride layer, barrier layer and second titanium nitride layer in the recess on the nFET portion conformally cover a bottom and a side of the nFET recess and the first titanium nitride layer, barrier layer, second titanium nitride layer and third titanium nitride layer in the recess on the pFET portion conformally cover a bottom and a side of the pFET recess.
 3. The CMOS device of claim 1 wherein the second titanium nitride layer in the recess on the nFET portion conformally covers a bottom and a side of the nFET recess and the third titanium nitride layer in the recess on the pFET portion conformally covers a bottom and a side of the pFET recess.
 4. The CMOS device of claim 1 wherein the second titanium nitride layer in the recess on the nFET portion is titanium-rich and the third titanium nitride layer in the recess on the pFET portion is titanium-rich, wherein titanium-rich is greater than 50 atomic percent titanium.
 5. The CMOS device of claim 1 wherein a composition of the second titanium nitride layer in the recess on the nFET portion is the same as a composition of the third titanium nitride layer in the recess on the pFET portion.
 6. The CMOS device of claim 5 wherein the second titanium nitride layer in the recess on the nFET portion is titanium-rich and the third titanium nitride layer in the recess on the pFET portion is titanium-rich, wherein titanium-rich is greater than 50 atomic percent titanium.
 7. The CMOS device of claim 1 wherein the gate metal filling each of the nFET recess and pFET recess comprises a first layer of titanium aluminum and a second layer of aluminum or tungsten.
 8. A CMOS device comprising: a semiconductor substrate having an nFET portion, a pFET portion and an interlayer dielectric between the nFET portion and pFET portion; the nFET portion having a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer in direct physical contact with the barrier layer and a gate metal filling the remainder of the recess, wherein the second titanium nitride layer is titanium-rich wherein titanium-rich is greater than 50 atomic percent titanium; the pFET portion having a gate structure, the gate structure comprising a recess filled with a conformal high-k dielectric on a bottom and a side of the recess, a first titanium nitride layer on the high-k dielectric, a barrier layer on the first titanium nitride layer, a second titanium nitride layer on the barrier layer, a third titanium nitride layer in direct physical contact with the second titanium nitride layer and a gate metal filling the remainder of the recess, wherein the third titanium nitride layer is titanium-rich, wherein titanium-rich is greater than 50 atomic percent titanium; and wherein the gate metal filling the remainder of each of the nFET recess and pFET recess comprises a first layer of titanium aluminum and a second layer of aluminum or tungsten.
 9. The CMOS device of claim 8 wherein the first titanium nitride layer, barrier layer and second titanium nitride layer in the recess on the nFET portion conformally cover a bottom and a side of the nFET recess and the first titanium nitride layer, barrier layer, second titanium nitride layer and third titanium nitride layer in the recess on the pFET portion conformally cover a bottom and a side of the pFET recess.
 10. The CMOS device of claim 8 wherein the second titanium nitride layer in the recess on the nFET portion conformally covers a bottom and a side of the nFET recess and the third titanium nitride layer in the recess on the pFET portion conformally covers a bottom and a side of the pFET recess.
 11. The CMOS device of claim 8 wherein a composition of the second titanium nitride layer in the recess on the nFET portion is the same as a composition of the third titanium nitride layer in the recess on the pFET portion. 